教科研成果 | 代表性课题： 山西省教育厅, 山西省高等学校科技创新项目, 项目名称：苯并环丁烯酮和不饱和组分经“切割-缝合”机理形成桥环化合物的理论研究, 起止时间: 2024.10-2026.12, 项目编号: 2024L284, 在研, 主持。 近5年发表论文： (1) Li J*, Li K, Qu S*.Unraveling the mechanism of Pd-catalyzed hydrocyanation of methylenecyclopropane or cyclopropene with Me2C(OH)CN: a DFT study. New J. Chem., 2026, 50, 8778–8783. (2) Li J*, Chen Z, Zhang Z-H, Yao Z, Yang T, Duan A*, Qu S*. Computational Exploration of Intramolecular Cycloaddition of Cyclobutanone with Alkene Catalyzed by Rhodium Versus Nickel: The Origins of Selectivities. J. Org. Chem., 2025, 90, 10570–10579. (3) Li J*, Deng Y, Li J, Guo Y, Wang G, Duan A*, Qu, S*. Mechanistic Study of Palladium-Catalyzed Ring-Opening/Cross-Coupling Reactions of Silacycles. Chinese J. Org. Chem., 2025, 45, 2938–2944. (4) Li J*, Chen W, Qu S*. DFT study of rhodium-catalyzed transformation of silacyclobutane with alkyne or H2O: Si–Cl bond reductive elimination vs. alkyne insertion. Org. Chem. Front., 2024, 11, 3663–3674. (5) Li J, Tang D, Zhang Y, Chen W, Su X, Yu P*, Qu S*. DFT Study of Ni-Catalyzed Intramolecular Asymmetric anti-Hydrometalative Cyclization of Alkynone: Mechanism and Origins of Selectivity. Org. Chem. Front., 2023, 10, 4263–4274. (6) Li J, Luo J, Tong W, Tang D, Zhang J, Zhang Z-H, Qu S*. Mechanistic Study of Nickel-Catalyzed Intramolecular [4+2] Cycloaddition of Cyclobutanone with Allene: Origin of Selectivity and Ligand Effect. Org. Chem. Front., 2023, 10, 1134–1146. |
